Get Activation of Unreactive Bonds and Organic Synthesis PDF

By Shinji Murai

ISBN-10: 3540648623

ISBN-13: 9783540648628

The primary suggestion of this quantity is to provide a Capita Selecta of unconventional and thought-provoking issues in organometallic chemistry, provided via specialists in each one box. As meant, this method leads both to reports protecting a particular unusual category of organometallic compounds or to overviews which relate unusual actual houses with quite a few periods of organometallic compounds. content material: constitution and electrochemistry of transition steel carbonyl clusters with interstitial or semi-interstitial atoms: distinction among nitrides or phosphides and carbides / Piero Zanello -- strange nuclear magnetic defensive and coupling constants regarding strange bonding occasions / Bernd Wrackmeyer -- Deuterium spin lattice rest and deuterium quadrupole coupling constants. a singular process for characterization of transition steel hydrides and dihydrogen complexes in resolution / Vladimir I. Bakhmutov -- NMR reports of ligand nuclei in organometallic compounds -- new details from solid-state NMR concepts / man M. Bernard, Roderick E. Wasylishen -- steel atom movement in a few iron organometallics / Rolfe H. Herber -- Magnetic conversation in binuclear organometallic complexes mediated by means of carbon-rich bridges / Frďřic Paul, Claude Lapinte -- Molecular cluster complexes with facial arene ligands / Herbert Wadepohl -- Cobaltafulvenes and cobaltapentalenes: hugely polar metallacyclic II-systems with strange houses / Herbert Wadepohl -- Novel hugely nucleophilic ylidic ligands for the practise of surprisingly strong steel complexes / Norbert Kuhn, Martin Göhner, Gernot Frenking, Yu Chen -- Supramolecular interactions in constructions of natural antimony and Bismuth compounds / Gabor Balz̀s, Hans Joachim Breunig. summary: The vital inspiration of this quantity is to supply a Capita Selecta of unconventional and thought-provoking themes in organometallic chemistry, provided by way of specialists in every one box. As meant, this procedure leads both to studies overlaying a selected unusual category of organometallic compounds or to overviews which relate unusual actual homes with numerous periods of organometallic compounds

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Extra resources for Activation of Unreactive Bonds and Organic Synthesis

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Dehydrogenative Silylation of Alkanes and Arenes . . . . . 61 64 4 Hydroacylation with Aldehydes. . . . . . . . . . . 3 Intramolecular Hydroacylation of Olefins . . . . . . . . Intermolecular Hydroacylation of Olefins . . . . . . . . Hydroacylation of Acetylenes . . . . . . . . . . . 2 Michael Addition and Aldol Reactions . . . . . . . . . Addition to Carbon-Carbon Multiple Bonds . . . . . . . 72 73 6 Conclusion . . . . . . . . . . .

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15) 30 William D. Jones 4 Electrophilic Alkane Activation While all of the electrophilic complexes described in Sect. 3 are believed to react via oxidative addition/reductive elimination pathways, several metal complexes are believed to react via a concerted four-center mechanism as shown at the top of Fig. 1c. All of these compounds have one feature in common, namely, no delectrons. Consequently, oxidative addition pathways are deemed too high in energy to be feasible. One of the earliest reports was by Watson using the lutetium complex Cp*2LuCH3.

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Activation of Unreactive Bonds and Organic Synthesis by Shinji Murai

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